Talk to everyone you meet as you travel along the Highroad and most will give you items including:
2 Antidotes, a Hi-Potions, and a Hunter's Spear.
You can also find an Ice Brand in a chest behind a monument on the left side.
You'll find Belgemine on the right side who you can challenge in an Aeon only battle.
If you beat her she gives you a Echo Ring otherwise she'll give you a Seeker's Ring.
On the next stretch of road, there's a chest with a Remedy on the right side.
A running man will give you a Red Ring if you can catch him.
The next section, someone will give you a Lv. 1 Key Sphere, 4 Antidotes, an Ether,
a Hi-Potion and 600 gil.
Talk to the boy before you examine the blitzball to get 3 Softs.
There's 2000 gil on the right side in a chest.
At the end of the section you can get 3 Eye Drops in the chest.
At the Inn, head outside to talk to Yuna.
In the morning, someone will give you a Lv. 1 Key Sphere.
When you try to leave, Rin will show up and give you the Al Bhed Primer VIII and 2 Mega-Potions.
Once you step outside you'll have to battle Chocobo Eater.
If you manage to push it off the cliff, you'll recieve 2 Lv. 1 Key Spheres.
Afterward, you'll be able to ride a chocobo for free so get one and continue on.
Keep a lookout for a yellow feather on the left side of the road.
Your chocobo can jump from there to reach the Heat Lance on the cliff.
Just after that, you'll find the Al Bhed Primer IX lying on the road.
When you get to the North End of the highroad, you can pick up 2 Hi-Potions in a chest.
Head southeast from there on your chocobo down to the valley.
Jump from the feather to reach a Thunder Blade and Scout.
Near the save sphere is a small trail that you can jump up with your chocobo to reach a Fortune Sphere.
At the end of the road, you'll find the Mars Crest.
Go back to the north gate and talk to the people there.
The guard on the left is taking donations for Operation Mi'ihen, if you give him gil, he'll give you stuff in return -
100 gil: Scout, 1000 gil: Ice Lance, 10000 gil: Moon Ring.
Talk to the guard on the right about Operation Mi'ihen.
When you go back, Seymour will show up and get you through.
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